Institute of Atomic and M d e c u l a r Sciences, Academia Sinica P 0 Box 73-166. Taipei, Taiman. R 0 C .b&STR.ACT Like typical alkenes, hllerenes can be oxidized by ozone. Epoxidation reaction takes place on G o . and CsoOn jn=1-5) are formed. l\lass spectrometry and chromatography identified the stable existence of tLvO isomers for the dioxides and three for the trioxides in the product mixtures. At lower temperatures, fragmentation occurs and results i.n the formation of the polar products. C: o and carbon nanotubes also react with ozone but at a much slower rate.
A dipole field directed mechanism is proposed to explain the change of orientation of nanocrystallites within biomimetic vaterite particles displaying a morphology change from spherulite to hexagonal prism.
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