Both microfluidics and atomic force microscopy have been used to quantify the forces between oil drops in the presence of complexes formed with anionic surfactant, sodium dodecyl sulphate, and neutral, water soluble polymer, poly(vinylpyrrolidone). Measurement and modelling of the interaction forces between both rigid and deformable surfaces demonstrated that the attraction between the drops is due to depletion forces, whereas the repulsive force is a combination of electrical double layer and steric forces, indicating complexes exist both in the bulk and at the drop interface. We developed a new microfluidic device to first form and then break-up chains of drops, where the drop break-up is sensitive to the underlying surface forces between the drops, not hydrodynamic drainage forces. The interaction behaviour between the force measurements and the microfluidic observations showed a strong correlation, where the observed adhesion between drops in the microfluidics is sensitive to the drop deformation and Laplace pressure. Correlation between the two techniques provides insight into the surface forces between drops in flowing systems. This work opens the possibility of developing high-throughput measurements of adhesive interactions between drops and has the potential utility in the formulation of emulsions.
The influence of nanoparticle shape, in particular the sphere to rod transition, on surface forces and consequently the properties of colloidal fluids is an interesting but not well investigated phenomenon. Here, the surface force behaviour of concentrated surfactant solutions containing cetyltrimethylammonium bromide and sodium salicylate with micelle shapes varying from slightly prolate to high aspect ratio rods was measured. Atomic force microscopy (AFM) with both rigid particle and soft droplet probes was used with comparisons and analysis made using the Chan-Dagastine-White model. It is observed that small changes to the micelle shape result in no discernable differences to the surface force behaviour, however, once the micelles are elongated significantly, the long range forces adjust in nature from oscillatory to that of a single attractive force well. This highlights the importance that nanocolloid shape has on the behaviour and properties of emulsions and other colloidal fluids, specifically for emulsion flocculation and handling in systems of rod and worm like micelles.
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