Controlling the assembly of graphene based nanosheets within a rubber matrix: Nanocomposite morphology probed by measuring gas permeation and dielectric properties AIP Conference Proceedings 1736, 020066 (2016) Abstract. The use of graphene as a filler in thermoplastics has already been investigated extensively. The mechanical properties as well as electrical and thermal conductivity of thermoplastics can be improved due to graphene. However, these studies were carried out in experimental scale, which allows a good dispersion of graphene because of a long residence time during melt mixing and because of the use of almost ideal graphene, which has a high specific surface and low number of layers. In this study the scientific findings are transferred into industrial practice. For that purpose, a corotating intermeshing twin screw extruder with limited residence time and limited shear energy input is used to produce graphene based polyamide 6 composites and short carbon fibre reinforced graphene based polyamide 6 composites. These composites are further processed by injection molding to produce specimens in order to determine the mechanical properties. In addition to the scale-up to industrial production, two types of graphene platelets are used, which are commercially available. This investigation reveals that the addition of 1 wt.-% commercially available graphene platelets to polyamide 6 improves Young´s modulus and tensile strength. Compared to pure polyamide 6 an improvement up to 20 % with regard to Young´s modulus and up to 15 % with regard to tensile strength can be achieved. The combination of short carbon fibre with graphene platelets in polyamide 6 enables an increase of Young´s modulus, which is higher than the additive effect.
Thermoplastic cellulose acetate (CA) is a bio-based polymer with optical, mechanical and thermal properties comparable to those of polystyrene (PS). The substitution of the predominant petrol-based PS in applications like foamed food trays can lead to a more sustainable economic practice. However, CA is also suitable for more durable applications as the biodegradability rate can be controlled by adjusting the degree of substitutions. The extrusion foaming of CA still has to overcome certain challenges. CA is highly hydrophilic and can suffer from hydrolytic degradation if not dried properly. Therefore, the influence of residual moisture on the melt viscosity is rather high. Beyond, the surface quality of foam CA sheets is below those of PS due to the particular foaming behaviour. This paper presents results of a recent study on extrusion foamed CA, using a two-component physical blowing agent system compromising HFO 1234ze as blowing agent and organic solvents as co-propellant. Samples with different co-propellants are processed on a laboratory single screw extruder at IKV. Morphology and surface topography are investigated with respect to the blowing agent composition and the die pressure. In addition, relationships between foam density, foam morphology and the propellants are analysed. The choice of the co-propellant has a significant influence on melt-strength, foaming behaviour and the possible blow-up ratio of the sheet. Furthermore, a positive influence of the co-propellant on the surface quality can be observed. In addition, the focus is laid on the effect of external contact cooling of the foamed sheets after the die exit
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