The optical trapping of Au nanoparticles with dimensions as small as 10 nm in the gap of plasmonic dipole antennas is demonstrated. Single nanoparticle trapping events are recorded in real time by monitoring the Rayleigh scattering spectra of individual plasmonic antennas. Numerical simulations are also performed to interpret the experimental results, indicating the possibility to trap nanoparticles only a few nanometers in size. This work unveils the potential associated with the integration of plasmonic trapping with localized surface plasmon resonance based sensing techniques, in order to deliver analyte to specific, highly sensitive regions ("hot spots").

Plasmonic effects associated with metallic nanostructures have been widely studied for color generation. It became apparent that highly saturated and bright colors are hard to obtain, and very small nanostructures need to be fabricated. To address this issue, in this study, we employ metal-insulator-metal sandwich nanodisks that support enhanced in-phase electric dipole modes, which are blue-shifted with respect to a single metal disk. The blue shift enables the generation of short wavelength colors with larger nanostructures. The radiation modes hybridize with the Wood's anomaly in periodic structures, creating narrow and high-resonance peaks in the reflection and deep valleys in the transmission spectra, thus producing vivid complementary colors in both cases. Full colors can be achieved by tuning the radius of the nanodisks and the periodicity of the arrays. Good agreement between simulations and experiments is demonstrated and analyzed in CIE1931, sRGB, and HSV color spaces. The presented method has potential for applications in imaging, data storage, ultrafine displays, and plasmon-based biosensors.

All experimental observations of the uptake of the four title compounds on calcite are consistent with the presence of a reactive bifunctional surface intermediate Ca(OH)(HCO3) that has been proposed in the literature. The uptake of CO2 and SO2 occurs on specific adsorption sites of crystalline CaCO3(s) rather than by dissolution in adsorbed water, H2O(ads). SO2 primarily interacts with the bicarbonate moiety whereas CO2, HNO3 and HCl all react first with the hydroxyl group of the surface intermediate. Subsequently, the latter two react with the bicarbonate group to presumably form Ca(NO3)2 and CaCl2.2H2O. The effective equilibrium constant of the interaction of CO2 with calcite in the presence of H2O(ads) is kappa = deltaCO2/(H2O(ads)[CO2]) = 1.62 x 10(3) bar(-1), where CO2 is the quantity of CO2 adsorbed on CaCO3. The reaction mechanism involves a weakly bound precursor species that is reversibly adsorbed and undergoes rate-controlling concurrent reactions with both functionalities of the surface intermediate. The initial uptake coefficients gamma0 on calcite powder depend on the abundance of H2O(ads) under the present experimental conditions and are on the order of 10(-4) for CO2 and 0.1 for SO2, HNO3 and HCl, with gamma(ss) being significantly smaller than gamma0 for HNO3 and HCl, thus indicating partial saturation of the uptake. At 33% relative humidity and 300 K there are 3.5 layers of H2O adsorbed on calcite that reduce to a fraction of a monolayer of weakly and strongly bound water upon pumping and/or heating.

The spatial evolution of compositions and sub‐structures inside focused‐electron‐beam‐deposited tips from dicobalt‐octacarbonyl Co2(CO)8 precursor at 25 keV and varying beam current (20 pA – 3 μA) is extensively studied for the first time by means of energy dispersive X‐ray spectroscopy, transmission electron microscopy, back‐scattered electron imaging, and ion‐induced secondary electron imaging. Transverse and longitudinal tip cross sections and lamellae were prepared by focused ion beam milling. Two sub‐structure types can be distinguished: a nano‐composite sub‐structure is grown during the initial deposition stage (small‐aspect‐ratio tips). It consists of cobalt nano‐crystals embedded in a carbonaceous matrix. A second distinct cobalt‐grain‐rich sub‐structure develops in high‐aspect ratio tips. Both sub‐structures vary in appearance and composition with increasing beam current: the initial nano‐composite sub‐structure increases in cobalt content and nano‐crystal size, and the cobalt‐grain sub‐structure develops polycrystal‐, texture‐, whisker‐, or platelet‐like habits. The directed precursor flux from a micro‐tube prevents a radial symmetry of the sub‐structures with respect to the impinging focused electron beam, at medium to high beam current. Homogeneous nano‐composite high‐resolution tips with small diameter and length were obtained at low beam current. Observations suggest an additional contribution to pure electron induced precursor molecule decomposition. The influence of electron beam heating and related chemical reactions is discussed.

We report on the fabrication and electrical characterization of functionalized solid-state nanopores in low stress silicon nitride membranes. First, a pore of ∼50 nm diameter was drilled using a focused ion beam technique, followed by the local deposition of silicon dioxide. A low-energy electron beam induced the decomposition of adsorbed tetraethyl orthosilicate resulting in site-selective functionalization of the nanopore by the formation of highly insulating silicon oxide. The deposition occurs monolayer by monolayer, which allows for control of the final diameter with subnanometer accuracy. Changes in the pore diameter could be monitored in real time by scanning electron microscopy. Recorded ion currents flowing through a single nanopore revealed asymmetry in the ion conduction properties with the sign of the applied potential. The low-frequency excess noise observed at negative voltage originated from stepwise conductance fluctuations of the open pore.