The utilization of biogas produced from organic materials such as agricultural wastes or manure is increasing. However, the raw biogas contains a large share of carbon dioxide which must be removed before utilization in many applications, for example, using the gas as vehicle fuel. The process – biogas upgrading – can be performed with several technologies: water scrubbing, organic solvent scrubbing, amine scrubbing, pressure swing adsorption (PSA), and gas separation membranes. This perspective presents the technologies that are used commercially for biogas upgrading today, recent developments in the field and compares the technologies with regard to aspects such as technology maturity, investment cost, energy demand and consumables. Emerging technologies for small‐scale upgrading and future applications of upgraded biogas such as liquefied biogas are also discussed. It shows that the market situation has changed rapidly in recent years, from being totally dominated by pressure swing adsorption (PSA) and water scrubbing to being more balanced with new technologies (amine scrubbing) reaching significant market shares. There are significant economies of scale for all the technologies investigated, the specific investment costs are similar for plants with a throughput capacity of 1500 Nm3 raw biogas per hour or larger. Biogas production is increasing in Europe and around the globe, and so is the interest in the efficient use of upgraded biogas as vehicle fuel or in other applications. The market for biogas upgrading will most likely be characterized by harder competition with the establishment of new upgrading technologies and further optimization of the mature ones to decrease operation costs. © 2013 Society of Chemical Industry and John Wiley & Sons, Ltd

Lignin is a major component of lignocellulosic biomass and as such, it is processed in enormous amounts in the pulp and paper industry worldwide. In such industry it mainly serves the purpose of a fuel to provide process steam and electricity, and to a minor extent to provide low grade heat for external purposes. Also from other biorefinery concepts, including 2nd generation ethanol, increasing amounts of lignin will be generated. Other uses for lignin - apart from fuel production - are of increasing interest not least in these new biorefinery concepts. These new uses can broadly be divided into application of the polymer as such, native or modified, or the use of lignin as a feedstock for the production of chemicals. The present review focuses on the latter and in particular the advances in the biological routes for chemicals production from lignin. Such a biological route will likely involve an initial depolymerization, which is followed by biological conversion of the obtained smaller lignin fragments. The conversion can be either a short catalytic conversion into desired chemicals, or a longer metabolic conversion. In this review, we give a brief summary of sources of lignin, methods of depolymerization, biological pathways for conversion of the lignin monomers and the analytical tools necessary for characterizing and evaluating key lignin attributes.

The main objective has been to describe different cases of the methanol production from steel-work off gases (Coke oven gas and Basic oxygen furnace gas) and biomass based synthesis gas. The SSAB steel mill in the town of Luleå, Sweden has been used as a basis to analyze four different methanol production cases. The studied biomass gasification technology is based on a fluidized bed gasifier unit, where the production capacity is determined from case to case coupled to the heat production required to satisfy the local district heating demand. Critical factors are the integration of the gases with availability to the synthesis unit, to balance the steam system of the biorefinery and to meet the district heat demand of Luleå. For each case, the annual production potential of methanol, the overall production efficiencies and the effects on the total steel plant have been estimated.

The production of nitrogen fertilizers are almost exclusively based on fossil feedstocks such as natural gas and coal. Nitrogen fertilizers are a necessity to maintain the high agricultural production that the world's population currently demands. Ammonia produced from nonfossil-based feedstocks would enable renewable production of ammonia. Renewable feedstocks are one thing, but perhaps even more important in the future are the security of supply that decentralized production enables. In this study, the technoeconomic evaluation of production of ammonia from various renewable feedstocks and for several plant sizes was investigated. The feedstocks included in this study are gridbased electricity produced from wind power, biogas, and woody biomass. The feedstocks differed in exergy, and to make a fair comparison, the electric equivalence ratios method was used. The results showed that the energy consumption for biogas and electricity is the same at 42 GJ/ tonne ammonia. When using the electric equivalence comparison for the same cases, the results are 26 and 42 GJ/ tonne, respectively. Biomass-based production has an energy consumption of 58 GJ/tonne and 31 GJ/tonne when using the electric equivalence comparison, which should be compared with the industrial average of 37 GJ (or 21 GJ electric equivalence) per tonne of ammonia. Monte Carlo simulations were used to vary the inputs to the process to evaluate the production cost. The ammonia production cost ranged from $680 to 2300/tonne ammonia for the various cases studied.