Due to the increasing demand for battery raw materials such as cobalt, nickel, manganese, and lithium, the extraction of these metals not only from primary, but also from secondary sources like spent lithium-ion batteries (LIBs) is becoming increasingly important. One possible approach for an optimized recovery of valuable metals from spent LIBs is a combined pyro- and hydrometallurgical process. According to the pyrometallurgical process route, in this paper, a suitable slag design for the generation of slag enriched by lithium and mixed cobalt, nickel, and copper alloy as intermediate products in a laboratory electric arc furnace was investigated. Smelting experiments were carried out using pyrolyzed pelletized black mass, copper(II) oxide, and different quartz additions as a flux to investigate the influence on lithium-slagging. With the proposed smelting operation, lithium could be enriched with a maximum yield of 82.4% in the slag, whereas the yield for cobalt, nickel, and copper in the metal alloy was 81.6%, 93.3%, and 90.7% respectively. The slag obtained from the melting process is investigated by chemical and mineralogical characterization techniques. Hydrometallurgical treatment to recover lithium is carried out with the slag and presented in part 2.
Magnesium carbonate powders are essential in the manufacture of basic refractories capable of withstanding extremely high temperatures and for special types of cement and powders used in the paper, rubber, and pharmaceutical industries. A novel synthesis route is based on CO2 absorption/sequestration by minerals. This combines the global challenge of climate change with materials development. Carbon dioxide has the fourth highest composition in earth’s atmosphere next to nitrogen, oxygen and argon and plays a big role in global warming due to the greenhouse effect. Because of the significant increase of CO2 emissions, mineral carbonation is a promising process in which carbon oxide reacts with materials with high metal oxide composition to form chemically stable and insoluble metal carbonate. The formed carbonate has long-term stability and does not influence the earth’s atmosphere. Therefore, it is a feasible and safe method to bind carbon dioxide in carbonate compounds such as magnesite. The subject of this work is the carbonation of an olivine (Mg2SiO4) and synthetic magnesia sample (>97 wt% MgO) under high pressure and temperature in an autoclave. Early experiments have studied the influence of some additives such as sodium bicarbonate, oxalic acid and ascorbic acid, solid/liquid ratio, and particle size on the carbonation efficiency. The obtained results for carbonation of olivine have confirmed the formation of magnesium carbonate in the presence of additives and complete carbonation of the MgO sample in the absence of additives.
Silicon dioxide nanoparticles, also known as silica nanoparticles or nanosilica, are the basis for a great deal of biomedical and catalytic research due to their stability, low toxicity and ability to be functionalized with a range of molecules and polymers. A novel synthesis route is based on CO2 absorption/sequestration in an autoclave by forsterite (Mg2SiO4), which is part of the mineral group of olivines. Therefore, it is a feasible and safe method to bind carbon dioxide in carbonate compounds such as magnesite forming at the same time as the spherical particles of silica. Indifference to traditional methods of synthesis of nanosilica such as sol gel, ultrasonic spray pyrolysis method and hydrothermal synthesis using some acids and alkaline solutions, this synthesis method takes place in water solution at 175 °C and above 100 bar. Our first experiments have studied the influence of some additives such as sodium bicarbonate, oxalic acid and ascorbic acid, solid/liquid ratio and particle size on the carbonation efficiency, without any consideration of formed silica. This paper focuses on a carbonation mechanism for synthesis of nanosilica under high pressure and high temperature in an autoclave, its morphological characteristics and important parameters for silica precipitation such as pH-value and rotating speed.
Due to the increasing demand for battery raw materials, such as cobalt, nickel, manganese, and lithium, the extraction of these metals, not only from primary, but also from secondary sources, is becoming increasingly important. Spent lithium-ion batteries (LIBs) represent a potential source of raw materials. One possible approach for an optimized recovery of valuable metals from spent LIBs is a combined pyro- and hydrometallurgical process. The generation of mixed cobalt, nickel, and copper alloy and lithium slag as intermediate products in an electric arc furnace is investigated in part 1. Hydrometallurgical recovery of lithium from the Li slag is investigated in part 2 of this article. Kinetic study has shown that the leaching of slag in H2SO4 takes place according to the 3-dimensional diffusion model and the activation energy is 22–24 kJ/mol. Leaching of the silicon from slag is causing formation of gels, which complicates filtration and further recovery of lithium from solutions. The thermodynamic study presented in the work describes the reasons for the formation of gels and the possibilities of their prevention by SiO2 precipitation. Based on these findings, the Li slag was treated by the dry digestion (DD) method followed by dissolution in water. The silicon leaching efficiency was significantly reduced from 50% in the direct leaching experiment to 5% in the DD experiment followed by dissolution, while the high leaching efficiency of lithium was maintained. The study takes into account the preparation of solutions for the future trouble-free acquisition of marketable products from solutions.
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