Conducting polymer nanocoatings render plastics to possess interesting optical, chemical, and electrical properties. It nevertheless remains technically challenging to deposit uniform conducting polymer nanocoatings on ambient plastic substrates ascribed to the inert and varied chemical properties of plastics and the notorious processability of conducting polymers. Previous studies have made progress in delivering various conducting polymer thin films via oxidative chemical vapor deposition. Herein, we develop a solution-based approach to polyaniline (PANI) and PEGylated PANI nanocoatings on multiple engineering plastics followed by evaluating their antifouling performance. The procedure relies on the formation of uniform, lyotropic V2O5·nH2O thin films on plastics assisted by a surfactantsodium N-lauroylsarcosinate. Next, in situ, oxidative polymerization causes the formation of nanofibrous PANI nanocoatings. Finally, interfacial functionalization leads to PEGylated PANI nanocoatings, and the steric nanolayer effectively repels the adsorption of bovine serum albumin and the attachment of the bacterium Pseudoalteromonas sp. on the surface. It is worth noting that the antifouling properties rely mainly on the presence of PEGylated PANI nanocoatings, irrespective of the type of plastic substrates underneath. The current study therefore opens an avenue for the solution-based delivery of conducting polymer-based, functional nanocoatings on hydrophobic substrates in a controllable manner with the availability of further modification.
An increase of the stability of wood in fire is pivotal for its revival as a construction material. Nanotechnology exemplified by surface coating and impregnation has been developed to implement flame-retardant wood with arguable success. Inspired by the design principle of biological cellular structure, we introduced aerogels consisting of layered double hydroxide-polyaniline core–shell nanofibers in wood compartments. The impregnation of a lightweight flame-retardant network integrated the composite wood with excellent nonflammability. We demonstrate that this bioinspired design principle integrating flame-retardancy with the inherent merits of wood can be extended for the development of wood-based, lightweight hybrids with durability and multifunctionality.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.