A simple, mild and efficient approach to access fluorinated dibenz[b,e]azepines via visible-light photoredox catalysis is presented.

The first example of using commercially available and cheap nBu4NBr as cocatalyst, which is photoactivated by 4-CzIPN, to selectively activate the α-C-H bond of tetrahydrofuran for C-S and C-C cross-couplings...

A simple photoredox-neutral approach was reported for three-component thiohydroxylation, thioalkoxylation and thioamination of vinylarenes towards valuable vicinal S,O- and S,N- disubstituted molecules. N-phenyl-sulfenyl phthalimide, a communly used sulfur electrophile, was...

Herein, the design and synthesis of an unprecedented cobaloxime-based zirconium metal-organic framework (Zr-TCPCo) with an she net is reported. This heterogeneous material as a photocatalyst exhibits excellent catalytic activity for...

A simple and transition-metal-free HFIP-induced allylation reaction of tertiary allylic alcohols with thiols or sulfonyl hydrazine derivatives was reported for the efficient and highly selective synthesis of allylic sulfides and allylic sulfones. Herein, HFIP played a vital role in not only activating the allylic alcohol, but also stabilizing the allylic cation intermediate to accelerate the subsequent transformations.