Cathodoluminescence (CL) and photoluminescence (PL) of nickel oxide (NiO) have been investigated. The observed emission bands in the visible and near infrared spectral ranges are attributed to Ni2+ intraionic transitions. Some of the features observed in the CL spectra recorded from vacuum annealed samples are tentatively attributed to electronic transitions involving defect‐induced states located inside the charge‐transfer gap of this transition metal oxide.
Exchange anisotropy has been observed and investigated in single-crystalline CuO nanowires grown by thermal oxidation of Cu. The exchange bias field decreases by increasing temperature and can be tuned by the strength of the cooling field. A training effect has also been observed. The obtained results can be understood in terms of a phenomenological core-shell model, where the core of the CuO nanowire shows antiferromagnetic behavior and the surrounding shell behaves as a spin glass-like system due to uncompensated surface spins.
The formation of different phases of Bi 2 O 3 induced by laser irradiation of Bi films has been assessed in situ by micro-Raman spectroscopy as a function of laser wavelength, power density and irradiation time. Raman mapping of the irradiated samples enabled a spatially-resolved study of the distribution of the formed Bi 2 O 3 phases. Red laser (633 nm) irradiation was found to induce the appearance of b-Bi 2 O 3 , within a certain range of power densities, by diffusion-controlled processes. In contrast, ultraviolet (UV, 325 nm) laser irradiation, above a certain power density threshold, initially induces the formation of both b and d-Bi 2 O 3 phases. The amount of the produced d-Bi 2 O 3 phase increases by increasing the irradiation time, while that of the b phase follows the opposite trend. UV laser irradiation seems to be a suitable method to produce room temperature stable d-Bi 2 O 3 patterns on Bi films.
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