We report a new technique to enhance the electrical conductivity of transparent single-walled carbon nanotube (SWNT) films with a negligible loss of their optical transmittance. Hybridization of the SWNT films with gold nanoparticles increased the electrical conductivity 2-fold to a maximum of 2.0 × 105 S/m while maintaining the transmittance of the initial value. The same trends are shown for other SWNT films with various initial conductivities and transparency levels. Functional changes in the gold-nanoparticle-coated SWNT films suggest that the electrical conductivity change is due to an electron depletion mechanism as a result of a doping effect.

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The increasing demand for graphene has required a new route for its mass production without causing extreme damages. Here we demonstrate a simple and cost-effective intercalation based exfoliation method for preparing high quality graphene flakes, which form a stable dispersion in organic solvents without any functionalization and surfactant. Successful intercalation of alkali metal between graphite interlayers through liquid-state diffusion from ternary KCl-NaCl-ZnCl(2) eutectic system is confirmed by X-ray diffraction and X-ray photoelectric spectroscopy. Chemical composition and morphology analyses prove that the graphene flakes preserve their intrinsic properties without any degradation. The graphene flakes remain dispersed in a mixture of pyridine and salts for more than 6 months. We apply these results to produce transparent conducting (∼930 Ω/□ at ∼75% transmission) graphene films using the modified Langmuir-Blodgett method. The overall results suggest that our method can be a scalable (>1 g/batch) and economical route for the synthesis of nonoxidized graphene flakes.

The use of carbon nanotubes (CNTs) as transparent conducting films is one of the most promising aspects of CNT-based applications due to their high electrical conductivity, transparency, and flexibility. However, despite many efforts in this field, the conductivity of carbon nanotube network films at high transmittance is still not sufficient to replace the present electrodes, indium tin oxide (ITO), due to the contact resistances and semi-conducting nanotubes of the nanotube network films. Many studies have attempted to overcome such problems by the chemical doping and hybridization of conducting guest components by various methods, including acid treatment, deposition of metal nanoparticles, and the creation of a composite of conducting polymers. This review focuses on recent advances in surface-modified carbon nanotube networks for transparent conducting film applications. Fabrication methods will be described, and the stability of carbon nanotube network films prepared by various methods will be demonstrated.