Loss of oxygen in layered transition-metal oxides is a major reason for the structural degradation and thus the fade of electrochemical performance in the cathodes for Li-ion batteries. Via in situ transmission electron microscopy observations of LiNi 0.80 Co 0.15 Al 0.05 O 2 (NCA), we found that the oxygen loss in the layered cathode is a twostage process with distinct release rates. The initial rapid oxygen loss generates a high concentration of oxygen vacancies, which results in the formation of an amorphized, vacancy-containing rock-salt layer in the surface. In the second stage, the slower rate of oxygen loss allows recrystallization of this defective phase via coalescing of atomic oxygen vacancies, which results in the formation of a cavity-containing surface layer with a crystalline rock-salt structure over the layered phase in the bulk. Comparison of the in situ results with electrochemically cycled NCA cathodes confirms this two-stage process of oxygen loss. These results provide unprecedented microscopic details regarding the structural degradation of layered oxides arising from oxygen loss and have broader implications in manipulating the oxygen activity in the electrode.
Unlocking the full performance capabilities of battery materials will require a thorough understanding of the underlying electrochemical mechanisms at a variety of length scales. A broad arsenal of X-ray microscopy and mapping techniques is now available to probe these processes down to the nanoscale. The tunable nature of X-ray sources allows for the extraction of chemical states through spectromicroscopy. The addition of phase contrast imaging can retrieve the complex-valued refraction of the material, giving an even more nuanced chemical picture. Tomography and coherent Bragg diffraction imaging provide a reconstructed three-dimensional volume of the specimen, as well as internal strain information from the latter. Many recent insights into battery materials have been achieved through the creative use of these, and similar, methods. Experiments performed while the battery is being actively cycled reveal behavior that differs significantly from what is observed at equilibrium and metastable conditions. Planned improvements to X-ray source brightness and coherence will extend these techniques by alleviating the current trade-off in time, chemical, and spatial resolution.
The surface configuration of pristine layered oxide cathode particles for Li-ion batteries significantly affects the electrochemical behavior, which is generally considered to be a thin rock-salt layer in the surface. Unfortunately, aside from its thin nature and spatial location on the surface, the true structural nature of this surface rocksalt layer remains largely unknown, creating the need to understand its configuration and the underlying mechanisms of formation. Using scanning transmission electron microscopy, we have found a correlation between the surface rock-salt formation and the crystal facets on pristine LiNi 0.80 Co 0.15 Al 0.05 O 2 primary particles. It is found that the originally (014̅ ) and ( 003) surfaces of the layered phase result in two kinds of rock-salt reconstructions: the (002) and (111) rock-salt surfaces, respectively. Stepped surface configurations are generated for both reconstructions. The (002) configuration is relatively flat with monatomic steps while the (111) configuration shows significant surface roughening. Both reconstructions reduce the ionic and electronic conductivity of the cathode, leading to a reduced electrochemical performance.
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