Synthesis and characterization of soluble analogues of iodosylbenzene PhIO and (tosyliminoiodo)benzene PhINTs are reported. The syntheses of 4-trifluoromethyl-2-(tertbutylsulfonyl)iodosylbenzene (3) and 4-trifluoromethyl-2-(tert-butylsulfonyl)-(tosylimino)iodobenzene (4) increase the repertoire of available soluble organoiodine(III) based oxo-and nitrene precursors. We also report the synthesis of a new organoiodine(V) compound, 4-trifluoromethyl-2-(tert-butylsulfonyl)iodylbenzene.
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