The effect of ZnO defects on photoexcited charge carrier recombination and forward induced charge transfer was studied in organic-inorganic bilayer organic heterojunction solar cells. Decreased bimolecular recombination via passivation of ZnO nanopariticle defects resulted in longer carrier lifetime as determined by transient photovoltage (TPV) measurements. It was also found by time-resolved photoluminescence (TRPL) measurements that defect passivation decreased the fluorescence lifetime which indicated higher exciton dissociation efficiency. Through passivation of the ZnO nanoparticles defects, the two loss mechanisms were reduced and the power conversion efficiency (PCE) is significantly enhanced.

Nanoparticles can have a profound effect on thermal transitions observed in polymer nanocomposites. Many layer-by-layer (LbL) assemblies contain nanoparticles for added functionality, but the resulting effects of nanoparticles on an LbL film's thermal properties are not known. Previously, we have shown that a nanoparticle-free LbL film containing strong polyelectrolytes, poly(diallyldimethylammonium chloride)/poly(styrene sulfonate) (PDAC/PSS), exhibited a single reversible thermal transition much like a glass-melt transition. In the work presented here, nanoparticles of either spherical (SiO2) or platelet (Laponite clay) shape are inserted at varying vertical locations throughout PDAC/PSS LbL films. Temperature-controlled quartz crystal microbalance (QCM-D) and modulated differential scanning calorimetry (MDSC) are applied, for which QCM-D proved to be more sensitive to the transition. All Laponite-containing films possess two thermal transitions. During growth, Laponite-containing films exhibit steady increases in dissipation, which is proposed to arise from mechanically decoupled regions separated by the Laponite nanoparticles. For SiO2-containing films, three transitions are detectable only when the SiO2 nanoparticles are placed in the middle of the film; no transitions are observed for SiO2 placed at the bottom or top, perhaps because of a weakening of the transition. The lowest transition is close in value to that of neat PDAC/PSS LbL films, and was assigned to a "bulk" response. The higher transition(s) is attributed to polymer chains in an interfacial region near the nanoparticle. We propose that nanoparticles restrict segmental mobility, thus elevating the transition temperature in the interfacial region.