Complex heterostructured nanoparticles with precisely defined materials and interfaces are important for many applications. However, rationally incorporating such features into nanoparticles with rigorous morphology control remains a synthetic bottleneck. We define a modular divergent synthesis strategy that progressively transforms simple nanoparticle synthons into increasingly sophisticated products. We introduce a series of tunable interfaces into zero-, one-, and two-dimensional copper sulfide nanoparticles using cation exchange reactions. Subsequent manipulation of these intraparticle frameworks yielded a library of 47 distinct heterostructured metal sulfide derivatives, including particles that contain asymmetric, patchy, porous, and sculpted nanoarchitectures. This generalizable mix-and-match strategy provides predictable retrosynthetic pathways to complex nanoparticle features that are otherwise inaccessible.
Integrating multiple materials in arbitrary arrangements within nanoparticles is a prerequisite for advancing many applications. Strategies to synthesize heterostructured nanoparticles are emerging, but they are limited in complexity, scope, and scalability. We introduce two design guidelines, based on interfacial reactivity and crystal structure relations, that enable the rational synthesis of a heterostructured nanorod megalibrary. We define synthetically feasible pathways to 65,520 distinct multicomponent metal sulfide nanorods having as many as 6 materials, 8 segments, and 11 internal interfaces by applying up to seven sequential cation-exchange reactions to copper sulfide nanorod precursors. We experimentally observe 113 individual heterostructured nanorods and demonstrate the scalable production of three samples. Previously unimaginable complexity in heterostructured nanorods is now routinely achievable with simple benchtop chemistry and standard laboratory glassware.
The rational synthesis of metastable
inorganic solids, which is
a grand challenge in solid-state chemistry, requires the development
of kinetically controlled reaction pathways. Topotactic strategies
can achieve this goal by chemically modifying reactive components
of a parent structure under mild conditions to produce a closely related
analogue that has otherwise inaccessible structures and/or compositions.
Refractory materials, such as transition metal borides, are difficult
to structurally manipulate at low temperatures because they generally
are chemically inert and held together by strong covalent bonds. Here,
we report a multistep low-temperature topotactic pathway to bulk-scale
Mo2AlB2, which is a metastable phase that has
been predicted to be the precursor needed to access a synthetically
elusive family of 2-D metal boride (MBene) nanosheets. Room-temperature
chemical deintercalation of Al from the stable compound MoAlB (synthesized
as a bulk powder at 1400 °C) formed highly strained and destabilized
MoAl1–x
B, which was size-selectively
precipitated to isolate the most reactive submicron grains and then
annealed at 600 °C to deintercalate additional Al and crystallize
Mo2AlB2. Further heating resulted in topotactic
decomposition into bulk-scale Mo2AlB2–AlO
x
nanolaminates that contain Mo2AlB2 nanosheets with thickness of 1–3 nm interleaved
by 1–3 nm of amorphous aluminum oxide. The combination of chemical
destabilization, size-selective precipitation, and low-temperature
annealing provides a potentially generalizable kinetic pathway to
metastable variants of refractory compounds, including bulk Mo2AlB2 and Mo2AlB2–AlO
x
nanosheet heterostructures, and opens the
door to other previously elusive 2-D materials such as 2-D MoB (MBene).
The precise placement of different materials in specific regions of a nanocrystal is important for many applications, but this remains difficult to achieve synthetically. Here we show that regioselectivity during partial cation exchange reactions of metal chalcogenide nanocrystals emerges from crystallographic relationships between the precursor and product phases. By maximizing the formation of low-strain interfaces, it is possible to rationally integrate three distinct materials within uniform spherical and rod-shaped colloidal nanoparticles to produce complex asymmetric heterostructured isomers. Through sequential partial exchange of Cu in CuS nanocrystals with Zn and Cd, five distinct ZnS/CdS/CuS nanosphere and nanorod isomers are accessible.
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