Recurring discoveries of abiotic methane in gas seeps and springs in ophiolites and peridotite massifs worldwide raised the question of where, in which rocks, methane was generated. Answers will impact the theories on life origin related to serpentinization of ultramafic rocks, and the origin of methane on rocky planets. Here we document, through molecular and isotopic analyses of gas liberated by rock crushing, that among the several mafic and ultramafic rocks composing classic ophiolites in Greece, i.e., serpentinite, peridotite, chromitite, gabbro, rodingite and basalt, only chromitites, characterized by high concentrations of chromium and ruthenium, host considerable amounts of 13C-enriched methane, hydrogen and heavier hydrocarbons with inverse isotopic trend, which is typical of abiotic gas origin. Raman analyses are consistent with methane being occluded in widespread microfractures and porous serpentine- or chlorite-filled veins. Chromium and ruthenium may be key metal catalysts for methane production via Sabatier reaction. Chromitites may represent source rocks of abiotic methane on Earth and, potentially, on Mars.

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This study aims at the interpretation of the adverse effects of the secondary products in two types of rocks during their performance as concrete aggregates. Serpentinised peridotites contain serpentine, as the dominant secondary phase, which creates low microroughness on the particles and therefore unfavorable surfaces for cement paste to adequately adhere to. Moreover, its soft and platy nature contributes to the development of platy defects along the contacts of the aggregate particles with the cement paste. Poor adherence of the paste, failures along the contacts of the aggregate particles and potential propagation of the defects into the concrete during curing (and perhaps subsequently in-service) explain the poor performance of highly serpentinised rocks as concrete aggregates. Andesites show a different composition with a variety of secondary products including albite, chlorite, calcite, Fe-oxides and clay minerals. The role of all these products was investigated and it appears that only smectite is important, as even small amounts of it may be detrimental to the quality of the rocks as concrete aggregates. It is likely that abnormal hydration reactions and considerable swelling of the smectite result in the appearance of defects in the concrete, hence contributing to its low performance.