Blends were prepared from poly(lactic acid) (PLA) and thermoplastic starch (TPS) to study component interactions, structure and properties. Starch was plasticized with glycerol at two levels, at 36 and 47 wt%. The results unambiguously showed that the interaction of the two components is weak. The investigation of the possible partitioning of glycerol in the two phases indicated that most of the plasticizer is located in the TPS phase. Thermodynamic modeling predicted some dissolution of PLA in TPS which was assisted by the presence of the plasticizer, but TPS did not dissolve in PLA at all. No tangible proof was found for the formation of a glycerol rich phase in TPS, the relaxation transition assigned to this phase was rather explained with the movement of smaller structural units of starch molecules. Weak interfacial adhesion does not allow stress transfer through the interface resulting in poor strength and small deformation.
Graphene-like nanomaterials have received tremendous research interest due to their atomic thickness and fascinating properties. Previous studies mainly focus on the modulation of their electronic structures, which undoubtedly optimizes the electronic properties, but is not the only determinant of performance in practical applications. Herein, we propose a generalized strategy to incrementally manipulate the architectures of several atomically thin transition metal (hydr)oxides, and study their effects on catalytic water oxidation. The results demonstrate the obvious superiority of a wrinkled nanosheet architecture in both catalytic activity and durability. For instance, wrinkled Ni(OH) nanosheets display a low overpotential of 358.2 mV at 10 mA cm, a high current density of 187.2 mA cm at 500 mV, a small Tafel slope of 54.4 mV dec, and excellent long-term durability with gradually optimized performance, significantly outperforming other nanosheet architectures and previously reported catalysts. The outstanding catalytic performance is mainly attributable to the 3D porous network structure constructed by wrinkled nanosheets, which not only provides sufficient contact between electrode materials and current collector, but also offers highly accessible channels for facile electrolyte diffusion and efficient O escape. Our study provides a perspective on improving the performance of graphene-like nanomaterials in a wide range of practical applications.
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