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Abstract.We have computed physical parameters such as density, degree of ionization and temperature, constrained by a large observational data set on atomic and molecular species, for the line of sight toward the single cloud HD 147889. Diffuse interstellar bands (DIBs) produced along this line of sight are well documented and can be used to test the PAH hypothesis. To this effect, the charge state fractions of different polycyclic aromatic hydrocarbons (PAHs) are calculated in HD 147889 as a function of depth for the derived density, electron abundance and temperature profile. As input for the construction of these charge state distributions, the microscopic properties of the PAHs, e.g., ionization potential and electron affinity, are determined for a series of symmetry groups. The combination of a physical model for the chemical and thermal balance of the gas toward HD 147889 with a detailed treatment of the PAH charge state distribution, and laboratory and theoretical data on specific PAHs, allow us to compute electronic spectra of gas phase PAH molecules and to draw conclusions about the required properties of PAHs as DIB carriers. We find the following. 1) The variation of the total charge state distribution of each specific class (series) of PAH in the translucent cloud toward HD 147889 (and also of course for any other diffuse/translucent cloud) depends strongly on the molecular symmetry and size (number of π electrons). This is due to the strong effects of these parameters on the ionization potential of a PAH. 2) Different wavelength regions in the DIB spectrum are populated preferentially by different PAH charge states depending on the underlying PAH size distribution. 3) The PAH size distribution for HD 147889 is constrained by the observed DIB spectrum to be Gaussian with a mean of 50 carbon atoms.

The Large Magellanic Cloud (LMC) offers a unique laboratory to study the diffuse interstellar bands (DIBs) under conditions that are profoundly different from those in the Galaxy. DIB carrier abundances depend on several environmental factors, in particular the local UV radiation field. In this paper we present measurements of twelve DIBs in five lines of sight to early-type stars in the LMC, including the 30 Doradus region. From the high resolution spectra obtained with VLT/UVES we also derive environmental parameters that characterise the local interstellar medium (ISM) in the probed LMC clouds. These include the column density components (including total column density) for the atomic resonance lines of Na i, Ca ii, Ti ii, K i. In addition, we derive the H i column density from 21 cm line profiles, the total-to-selective visual extinction R V and the gas-to-dust ratio N(H i)/A V . Furthermore, from atomic line ratios we derive the ionisation balance and relative UV field strength in these environments. We discuss the properties of the LMC ISM in the context of DIB carrier formation. The behaviour of DIBs in the LMC is compared to that of DIBs in different local environmental conditions in the Milky Way. A key result is that in most cases the diffuse band strengths are weak (up to factor 5) with respect to Galactic lines of sight of comparable reddening, E B−V . In the line of sight towards Sk -69 223 the 5780 and 5797 Å DIBs are very similar in strength and profile to those observed towards HD 144217, which is typical of an environment exposed to a strong UV field. From the velocity analysis we find that DIB carriers (towards Sk -69 243) are better correlated with the ionised species like Ca ii than with neutrals (like Na i and CO). The most significant parameter that governs the behaviour of the DIB carrier is the strength of the UV field.

SummaryWe present spectral diagnostics for the fluxes of emission lines, in the spectral range 3600-4400 Å, during the cooling phase of stellar flares on dMe stars. Using these diagnostics, electron temperatures have been computed for flares on AD Leonis, Proxima Centauri and UV Ceti. This preliminary model assumes a single flare loop containing a homogeneous, stationary optically-thin flare plasma.

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C + 60 ) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C + 60 requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C + 60 9348, 9365, 9428 and 9577 Å absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C + 60 bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C + 60 bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C + 60 .