Abstract. Long-term measurements by the AERONET program of spectral aerosol optical depth, precipitable water, and derived Angstrom exponent were analyzed and compiled into an aerosol optical properties climatology. Quality assured monthly means are presented and described for 9 primary sites and 21 additional multiyear sites with distinct aerosol regimes representing tropical biomass burning, boreal forests, midlatitude humid climates, midlatitude dry climates, oceanic sites, desert sites, and background sites. Seasonal trends for each of these nine sites are discussed and climatic averages presented. IntroductionMan is altering the aerosol environment through land cover change, combustion of fossil fuels, and the introduction of particulate and gas species to the atmosphere. Each perturbation has some impact on the local aerosol environment. How much aerosol man is contributing to the atmosphere is not •øUniversity of New Mexico, Albuquerque, New Mexico.•qnstituto de Pesquisas Espaciais, Sao Jose dos Campos, San Paolo, Brazil.•2National Oceanic and Atmospheric Administration, Silver Spring, Maryland.•3Scripps Institute of Oceanography, La Jolla, California.•4Department of Applied Science, Brookhaven National Laboratory, Upton, New York.•SNow at Naval Research Laboratory, Washington, D.C.•6Ben Gurion University of the Negev, Sede Boker, Israel.•7CARTEL, Universit6 de Sherbrooke, Sherbrooke, Quebec, Canada.•sSAIC-GSC, Beltsville, Maryland, and NASA GSFC, Greenbelt, The simplest, and, in principle, the most accurate and easy to maintain monitoring systems are ground based. Aerosol optical depth is the single most comprehensive variable to remotely assess the aerosol burden in the atmosphere from groundbased instruments. This variable is used in local investigations to characterize aerosols, assess atmospheric pollution, and make atmospheric corrections to satellite remotely sensed data. It is for these reasons that a record of aerosol optical depth spanning most of the twentieth century has been measured from Sun photometers. The vast majority are site specific, short-term investigations with little relevance for seasonal, annual, or long-term trend analysis, however a few multiyear spatial studies have contributed to our knowledge and experience (Table 1). The following section reviews these investigations, past and present, which significantly addressed long-term measurements over widely distributed locations or provided a significant contribution that allowed development of a network for long-term photometric aerosol observations. The earliest systematic results come from the Smithsonian Institution solar observatories. Roosen e! al. [1973] computed extinction coefficients from 13 widely separated sites during the first half of the twentieth century using spectrobolometer observations by the Astrophysical Observatory of the Smithsonian Institution. They concluded the aerosol burden did not 12,067

[1] Aerosol mixtures composed of coarse mode desert dust combined with fine mode combustion generated aerosols (from fossil fuel and biomass burning sources) were investigated at three locations that are in and/or downwind of major global aerosol emission source regions. Multiyear monitoring data at Aerosol Robotic Network sites in Beijing (central eastern China), Kanpur (Indo-Gangetic Plain, northern India), and Ilorin (Nigeria, Sudanian zone of West Africa) were utilized to study the climatological characteristics of aerosol optical properties. Multiyear climatological averages of spectral single scattering albedo (SSA) versus fine mode fraction (FMF) of aerosol optical depth at 675 nm at all three sites exhibited relatively linear trends up to ∼50% FMF. This suggests the possibility that external linear mixing of both fine and coarse mode components (weighted by FMF) dominates the SSA variation, where the SSA of each component remains relatively constant for this range of FMF only. However, it is likely that a combination of other factors is also involved in determining the dynamics of SSA as a function of FMF, such as fine mode particles adhering to coarse mode dust. The spectral variation of the climatological averaged aerosol absorption optical depth (AAOD) was nearly linear in logarithmic coordinates over the wavelength range of 440-870 nm for both the Kanpur and Ilorin sites. However, at two sites in China (Beijing and Xianghe), a distinct nonlinearity in spectral AAOD in logarithmic space was observed, suggesting the possibility of anomalously strong absorption in coarse mode aerosols increasing the 870 nm AAOD.Citation: Eck, T. F., et al. (2010), Climatological aspects of the optical properties of fine/coarse mode aerosol mixtures,

[1] The column-integrated optical properties of aerosol in the central eastern region of Asia and midtropical Pacific were investigated based on Sun/sky radiometer measurements made at Aerosol Robotic Network (AERONET) sites in these regions. Characterization of aerosol properties in the Asian region is important due to the rapid growth of both population and economic activity, with associated increases in fossil fuel combustion, and the possible regional and global climatic impacts of related aerosol emissions. Multiyear monitoring over the complete annual cycle at sites in China, Mongolia, South Korea, and Japan suggest spring and/or summer maximum in aerosol optical depth (t a ) and a winter minimum; however, more monitoring is needed to establish accurate climatologies. The annual cycle of Angstrom wavelength exponent (a) showed a springtime minimum associated with dust storm activity; however, the monthly mean a 440 -870 was >0.8 even for the peak dust season at eastern Asian sites suggesting that fine mode pollution aerosol emitted from population centers in eastern Asia dominates the monthly aerosol optical influence even in spring as pollution aerosol mixes with coarse mode dust originating in western source regions. Aerosol optical depth peaks in spring in the tropical mid-Pacific Ocean associated with seasonal shifts in atmospheric transport from Asia, and $35% of the springtime t a500 enhancement occurs at altitudes above 3.4 km. For predominately fine mode aerosol pollution cases, the average midvisible ($550 nm) single scattering albedo (w 0 ) at two continental urban sites in China averaged $0.89, while it was significantly higher, $0.93, at two relatively rural coastal sites in South Korea and Japan. Differences in fine mode absorption between these regions may result from a combination of factors including aerosol aging during transport, relative humidity differences, sea salt at coastal sites, and fuel type and combustion differences in the two regions. For cases where t a was predominately coarse mode dust aerosol in the spring of 2001, the absorption was greater in eastern Asia compared to the source regions, with w 0 at Dunhuang, China (near to the major Taklamakan dust source), $0.04 higher than at Beijing at all wavelengths, and Anmyon, South Korea, showing an intermediate level of absorption. Possible reasons for differences in dust absorption magnitude include interactions between dust and fine mode pollution aerosol and also variability of dust optical properties from different source regions in China and Mongolia.