The relative retardation of intramolecular charge transfer (ICT) and the solvation dynamics of coumarin
152 in pure AOT, water, methanol, acetonitrile, and formamide reverse micelles have been investigated
using picosecond time-resolved emission spectroscopy. The rate of ICT has been retarded almost 7 times
at w
0 = 4 and 4 times at w
0 = 32 compared to that in pure water. The rate of retardation of ICT is also
observed in the methanol and acetonitrile reverse micelles in comparison to that in pure methanol and
acetonitrile. In pure AOT, the solvation time is 12.22 ns, but at w
0 = 4 of water reverse micelles the
solvation time is 7.27 ns. The slow dynamics in methanol, acetonitrile, and formamide reverse micelles
is also observed. The relative retardation of the ICT rate is much smaller compared to the several thousand
fold decrease in the solvation dynamics in the pool of the reverse micelles. The w dependency of solvation
time is observed for water and methanol reverse micelles, but it is little for acetonitrile and none for
formamide reverse micelles. The various w dependencies of solvation dynamics in water, methanol, and
acetonitrile reverse micelles are explained on the basis of the presence and the absence of hydrogen-bonding networks in water, methanol, and acetonitrile, respectively.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.