Cellulose is known to interact well with water, but is insoluble in it. Many polysaccharides such as cellulose are known to have significant hydrogen bond networks joining the molecular chains, and yet they are recalcitrant to aqueous solvents. This review charts the interaction of cellulose with water but with emphasis on the formation of both natural and synthetic fiber composites. Covering studies concerning the interaction of water with wood, the biosynthesis of cellulose in the cell wall, to its dispersion in aqueous suspensions and ultimately in water filtration and fiber-based composite materials this review explores water−cellulose interactions and how they can be exploited for synthetic and natural composites. The suggestion that cellulose is amphiphilic is critically reviewed, with relevance to its processing. Building on this, progress made in using various charged and modified forms of nanocellulose to stabilize oil−water emulsions is addressed. The role of water in the aqueous formation of chiral nematic liquid crystals, and subsequently when dried into composite films is covered. The review will also address the use of cellulose as an aid to water filtration as one area where interactions can be used effectively to prosper human life.
In this study, pulped cellulose fibres were pre-treated with aqueous morpholine prior to mechanical disruption in the production of cellulose nanofibrils (CNF). The properties of the morpholine pretreated CNF (MCNF) were closely compared with CNF obtained from carboxymethylation (CMCNF) and TEMPO-oxidation (TCNF) pre-treatment methods. An investigation of the swelling behaviours of cellulose in varying concentrations of morpholine revealed that there is a synergistic behaviour between morpholine and water in its ability to swell cellulose. As a result, cellulose pulp dispersed in 1:1 mole ratio of morpholine to water was well swollen and readily fibrillated by mechanical shear. Surface chemistry analyses indicated that the surface of the MCNF remained unmodified, compared to the CMCNF and TCNF which were modified with anionic groups. This resulted in only a slight decrease in crystallinity index and a minimal effect on the thermal stability of MCNF, compared to CMCNF and TCNF which showed marked decreases in crystallinity indices and thermal stabilities. The average widths of MCNF, CMCNF and TCNF, as measured from electron microscopic images, were broadly similar. The higher polydispersity of MCNF widths however led to a differential sedimentation and subsequent lower aspect ratio in comparison with CMCNF and TCNF as estimated using the sedimentation approach. Also, the presence of electrostatic repulsive forces, physical interactions/ entanglements and lower rigidity threshold of the CMCNF and TCNF resulted in higher storage moduli compared to the MCNF, whose elasticity is controlled by physical interactions and entanglements. Aqueous morpholine pre-treatment can potentially be regarded as an ecologically sustainable process for unmodified CNF production, since the chemical reagent is not consumed and can be recovered and reused.
Sodium (Na) is the most appealing alternative to lithium as an anode material for cost‐effective, high‐energy‐density energy‐storage systems by virtue of its high theoretical capacity and abundance as a resource. However, the uncontrolled growth of Na dendrites and the limited cell cycle life impede the large‐scale practical implementation of Na‐metal batteries (SMBs) in commonly used and low‐cost carbonate electrolytes. Herein, the employment of a novel bifunctional electrospun nanofibrous separator comprising well‐ordered, uniaxially aligned arrays, and abundant sodiophilic functional groups is presented for SMBs. By tailoring the alignment degree, this unique separator integrates with the merits of serving as highly aligned ion‐redistributors to self‐orientate/homogenize the flux of Na‐ions from a chemical molecule level and physically suppressing Na dendrite puncture at a mechanical structure level. Remarkably, unprecedented long‐term cycling performances at high current densities (≥1000 h at 1 and 3 mA cm−2, ≥700 h at 5 mA cm−2) of symmetric cells are achieved in additive‐free carbonate electrolytes. Moreover, the corresponding sodium–organic battery demonstrates a high energy density and prolonged cyclability over 1000 cycles. This work opens up a new and facile avenue for the development of stable, low‐cost, and safe‐credible SMBs, which could be readily extended to other alkali‐metal batteries.
In this study, surface chemistry, the morphological properties, water retention values, linear viscoelastic properties, crystallinity index, tensile strength and thermal properties of water hyacinth (WH) cellulose were correlated with the degree of mechanical processing under high-pressure homogenisation. An initial low-pressure mechanical shear of WH stems resulted in the ease of chemical extraction of good quality cellulose using mild concentrations of chemical reagents and ambient temperature. Further passes through the homogeniser resulted in an overall improvement in cellulose fibrillation into nanofibrils, and an increase in water retention property and linear viscoelastic properties as the number of passes increased. These improvements are most significant after the first and second pass, resulting in up to 7.5% increase in crystallinity index and 50% increase in the tensile strength of films, when compared with the unprocessed WH cellulose. The thermal stability of the WH cellulose was not adversely affected but remained stable with increasing number of passes. Results suggest a high suitability for this process to generate superior quality cellulose nanofibrils at relatively low energy requirements, ideal for sustainable packaging applications and as a structural component to bioplastic composite formulations.
Suspensions of cellulose micro-and nanofibrils are widely used in coatings, fibre spinning, 3D printing and as rheology modifiers where they are frequently exposed to shear rates [ 10 4 s -1, often within small confinements. High-shear rate rheological characterisation for these systems is therefore vital. Rheological data at high-shear rates are normally obtained using capillary and microfluidic rheometers, which are found in relative scarcity within research facilities compared to rotational rheometers. Also, secondary flows and wall depletion prevalent at such high-shear rates often go unnoticed or unquantified, rendering the measurement data unreliable. Reliable high shear rate rheometry using rotational rheometers is therefore desirable. Suspension of TEMPO-oxidised CMF/CNF was tested for its highshear rate rheological properties using parallel plate geometry at measurement gaps 150-40 lm and concentric cylinder at 1 mm gap. The errors from gap setting, radial dependence of shear stress and wall depletion were quantified and accounted for. Viscosity data from 0.1 to 30,000 s -1 shear rates was constructed using both geometries in agreement. Possibilities of secondary flows, radial migration of fluid and viscous heating were ruled out.Graphical abstract Steady shear flow data of CMF/ CNF suspension from 0.1 to 30,000 s -1 obtained using rotational rheometer
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