Here we present high-resolution (15-24 au) observations of CO isotopologue lines from the Molecules with ALMA on Planet-forming Scales (MAPS) ALMA Large Program. Our analysis employs observations of the (J = 2-1) and (1-0) lines of 13 CO and C 18 O and the (J = 1-0) line of C 17 O for five protoplanetary disks. We retrieve CO gas density distributions, using three independent methods: (1) a thermochemical modeling framework based on the CO data, the broadband spectral energy distribution, and the millimeter continuum emission; (2) an empirical temperature distribution based on optically thick CO lines; and (3) a direct fit to the C 17 O hyperfine lines. Results from these methods generally show excellent agreement. The CO gas column density profiles of the five disks show significant variations in the absolute value and the radial shape. Assuming a gas-to-dust mass ratio of 100, all five disks have a global CO-to-H 2 abundance 10-100 times lower than the interstellar medium ratio. The CO gas distributions between 150 and 400 au match well with models of viscous disks, supporting the longstanding theory. CO gas gaps appear to be correlated with continuum gap locations, but some deep continuum gaps do not have corresponding CO gaps. The relative depths of CO and dust gaps are generally consistent with predictions of planet-disk interactions, but some CO gaps are 5-10 times shallower than predictions based on dust gaps. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a unique opportunity to study the vertical distribution of gas, chemistry, and temperature in the protoplanetary disks around IMLup, GMAur, AS209, HD163296, and MWC480. By using the asymmetry of molecular line emission relative to the disk major axis, we infer the emission height(z) above the midplane as a function of radius(r). Using this method, we measure emitting surfaces for a suite of CO isotopologues, HCN, and C 2 H. We find that 12 CO emission traces the most elevated regions with > z r 0.3, while emission from the less abundant 13 CO and C 18 O probes deeper into the disk at altitudes of  z r 0.2. C 2 H and HCN have lower opacities and signal-to-noise ratios, making surface fitting more difficult, and could only be reliably constrained in AS209, HD163296, and MWC480, with  z r 0.1, i.e., relatively close to the planet-forming midplanes. We determine peak brightness temperatures of the optically thick CO isotopologues and use these to trace 2D disk temperature structures. Several CO temperature profiles and emission surfaces show dips in temperature or vertical height, some of which are associated with gaps and rings in line and/or continuum emission. These substructures may be due to local changes in CO column density, gas surface density, or gas temperatures, and detailed thermochemical models are necessary to better constrain their origins and relate the chemical compositions of elevated disk layers with those of planet-forming material in disk midplanes. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high-resolution (∼10–20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies—including rings, gaps, and plateaus—is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.