In the quest aimed at unveiling alternative plasmonic elements overcoming noble metals for selected applications in photonics, we investigate by numerical simulations the near ultraviolet-tonear infrared optical response of solid and liquid Bi nanospheres embedded in a dielectric matrix. We also determine the resulting transmission contrast upon reversible solid-liquid phase transition to evaluate their potential for switchable optical filtering. The optical response of the solid (liquid) Bi nanospheres is ruled by localized polaritonic (plasmonic) resonances tunable by controlling the diameter. For a selected diameter between 20 nm and 50 nm, both solid and liquid nanospheres present a dipolar resonance inducing a strong peak extinction in the near ultraviolet, however at different photon energies. This enables a high transmission contrast at selected near ultraviolet photon energies. It is estimated that a two-dimensional assembly of 30 nm solid Bi nanospheres with a surface coverage of 32% will almost totally extinct (transmission of 2%) a near ultraviolet 3.45 eV (359 nm) light beam, whereas upon phase transition the resulting liquid Bi nanospheres will show a transmission of 30%. This work appeals to the fabrication of locally reconfigurable optical metamaterials for integrated switchable near ultraviolet optics.

In this paper, we present a plasmonic refractometric sensor that works under normal incidence; allowing its integration on a fiber tip. The sensor's material and geometry exploit the large scattering cross-section given by high-contrast of the index of refraction subwavelength dielectric gratings. Our design generates a hybrid plasmonic-Fano resonance due to the interference between the surface plasmon resonance and the grating response. We optimize the sensor with a merit function that combines the quality parameter of the resonance and the field enhancement at the interaction volume where the plasmon propagates. Our device shows a high sensitivity (1000 nm/RIU) and a high Figure of Merit (775 RIU −1 ). Degradation in performance is negligible through a wide dynamic range up to 0.7 RIU. These quantitative parameters overperform compared to similar plasmonic sensors.

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A metallic nanostructured array that scatters radiation toward a thin metallic layer generates surface plasmon resonances for normally incident light. The location of the minimum of the spectral reflectivity serves to detect changes in the index of refraction of the medium under analysis. The normal incidence operation eases its integration with optical fibers. The geometry of the arrangement and the material selection are changed to optimize some performance parameters as sensitivity, figure of merit, field enhancement, and spectral width. This optimization takes into account the feasibility of the fabrication. The evaluated results of sensitivity (1020 nm/RIU) and figure of merit (614 RIU −1 ) are competitive with those previously reported.