The polyamide (PA)-12 material used for additive manufacturing was studied in aspects of morphology and their structural properties for basic stages received during 3D laser printing. Samples were real, big-scale production powders. The structure of polymer was evaluated from the crystallinity point of view using XRD, FTIR, and DSC methods and from the surface properties using specific surface evaluation and porosity. Scanning electron microscopy was used to observe morphology of the surface and evaluate the particle size and shape via image analysis. Results were confronted with laser diffraction particles size measurement along with an evaluation of the specific surface area. Fresh PA12 powder was found as inhomogeneous in particle size of material with defective particles, relatively high specific surface, high lamellar crystallite size, and low crystallinity. The scrap PA12 crystallinity was about 2% higher than values for fresh PA12 powder. Particles had a very low, below 1 m2/g, specific surface area; particles sintered as twin particles and often in polyhedral shapes.
This article deals with the adjustment of a 3D printer for laser engraving and material cutting. The print head can be fitted with a solid laser diode module, which achieves a compact size while retaining its useful power. Two paths lead to the use of such a concept. It is possible to equip the existing print head with a module, which also brings a number of disadvantages such as, for example, the reduction of the printing space or the need for a suitable mounting design. A more elegant solution is to consider this in the design of a 3D printer and design a system to exchange the print heads for 3D printing and laser engraving. Such a solution allows full utilization of the workspace and simple installation of the effector for the required type of work. According to the installed power of the laser diode, it is possible not only to engrave but also cut material such as thin wood, veneer or acrylic glass. The use of such a machine is not only for graphic elements but for the creation of various stencils, boxes or simple models, which can be made up of plastic-burning pieces. The laser module is controlled by a driver, which is designed for the device. This is connected to a 3D printer control board. It is, therefore, necessary for the control board to have at least two pins, which can be controlled after adjusting the control firmware. Most laser modules are normally equipped with an adjustable lens, which is used to concentrate the focus of a laser for the given distance against the worktop. Thus, the modified 3D printer can perform its function as a multi-purpose CNC machine, while a basic platform similar for both devices is used.
Printed circuit boards (PCBs) can be an important source of non-ferrous metals (Al, Sn, Zn, and Ni) and precious metals (Au, Ag, Cu, and Pd). With the continuous increase in demand for metals due to the depletion of ores, recycling of this waste is becoming an attractive alternative. The printed circuits also contain hazardous metals, such as Pb, Hg, As, and Cd. Due to the huge increase in the amount of e-waste, the processing of printed circuit boards for metal recovery and proper handling of hazardous substances has a positive effect on the environment. Pyrometallurgical and hydrometallurgical methods are used for the treatment of this waste. Various oxidizing agents are used in the hydrometallurgical processes, including ozone. PCBs from mobile phones were assessed for the recovery of Cu, Sn, and precious metals. The ground and sieved materials were leached in nitric acid, hydrochloric acid, and sulfuric acid at various process parameters, such as leaching time, leaching agent, and temperature. It was found that the best result was obtained using hydrochloric acid with the addition of ozone at 353 K for a period of 4 h to obtain 68.45 g/dm3 of copper. Preliminary results of electrolysis and cementation are also presented.
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