A new
class of thermally activated delayed fluorescent donor–acceptor–donor–acceptor
(D–A–D–A) π-conjugated macrocycle comprised
of two U-shaped electron-acceptors (dibenzo[a,j]phenazine) and two electron-donors (N,N′-diphenyl-p-phenyelendiamine)
has been rationally designed and successfully synthesized. The macrocyclic
compound displayed polymorphs-dependent conformations and emission
properties. Comparative studies on physicochemical properties of the
macrocycle with a linear surrogate have revealed significant effects
of the structural cyclization of the D–A-repeating unit, including
more efficient thermally activated delayed fluorescence (TADF). Furthermore,
an organic light-emitting diode (OLED) device fabricated with the
macrocycle compound as the emitter has achieved a high external quantum
efficiency (EQE) up to 11.6%, far exceeding the theoretical maximum
(5%) of conventional fluorescent emitters and that with linear analogue
(6.9%).
A dual-photofunctional organogermanium compound based on a donor–acceptor–donor architecture that exhibits thermally activated delayed fluorescence and mechano-responsive luminochromism has been developed. The developed compound was successfully applied as an emitter...
Two highly efficient commercial organic photosensitizers—azure A (AA) and 5-(4-aminophenyl)-10,15,20-(triphenyl)porphyrin (APTPP)—were covalently attached to the glass surface to form a photoactive monolayer. The proposed straightforward strategy consists of three steps, i.e., the initial chemical grafting of 3-aminopropyltriethoxysilane (APTES) followed by two chemical postmodification steps. The chemical structure of the resulting mixed monolayer (MIX_TC_APTES@glass) was widely characterized by X-ray photoelectron (XPS) and Raman spectroscopies, while its photoactive properties were investigated in situ by UV–Vis spectroscopy with α-terpinene as a chemical trap. It was shown that both photosensitizers retain their activity toward light-activated generation of reactive oxygen species (ROS) after immobilization on the glassy surface and that the resulting nanolayer shows high stability. Thanks to the complementarity of the spectral properties of AA and APTPP, the effectiveness of the ROS photogeneration under broadband illumination can be optimized. The reported light-activated nanocoating demonstrated promising antimicrobial activity toward Escherichia coli (E. coli), by reducing the number of adhered bacteria compared to the unmodified glass surface.
A new thermally activated delayed fluorescence (TADF)-displaying macrocyclic compound m-1 comprising of two electron-donors (N,N'-diphenyl-m-phenylenediamine) and two electron-acceptors (dibenzo[a,j]phenazine) has been synthesized. The macrocycle developed herein is regarded as a regioisomer of the previously reported TADF macrocycle p-1, which has two N,N'-diphenyl-p-phenylenediamines as the donors. To understand the influence of the topology of the phenylenediamine donors on physicochemical properties of TADF-active macrocycles, herein the molecular structure in the single crystals, photophysical properties, electrochemical behavior, and TADF properties of m-1 have been investigated compared with those of p-1. The substitution of p-phenylene donor with m-phenylene donor led to distinct positive solvatoluminochromism over the full visible-color range, unique oxidative electropolymerization, and slightly lower contribution of TADF, due to the lower CT character in the excited states.
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