Shot peening is a dynamically developing surface treatment used to improve the surface properties modified by tool, impact, microblasting, or shot action. This paper reviews the basic information regarding shot peening methods. The peening processes and effects of the shot peening and cavitation peening treatments on the surface layer properties of metallic components are analysed. Moreover, the effects of peening on the operational performance of metallic materials are summarized. Shot peening is generally applied to reduce the surface roughness, increase the hardness, and densify the surface layer microstructure, which leads to work hardening effects. In addition, the residual compressive stresses introduced into the material have a beneficial effect on the performance of the surface layer. Therefore, peening can be beneficial for metallic structures prone to fatigue, corrosion, and wear. Recently, cavitation peening has been increasingly developed. This review paper suggests that most research on cavitation peening omits the treatment of additively manufactured metallic materials. Furthermore, no published studies combine shot peening and cavitation peening in one hybrid process, which could synthesize the benefits of both peening processes. Moreover, there is a need to investigate the effects of peening, especially cavitation peening and hybrid peening, on the anti-wear and corrosion performance of additively manufactured metallic materials. Therefore, the literature gap leading to the scope of future work is also included.

Components produced by additive manufacturing (AM) via direct metal laser sintering (DMLS) have typical as-fabricated surface defects. As a result, surface properties of AM products should be modified to increase their strength, anti-wear behavior, and at the same time ensure their high corrosion resistance. Surface modification via shot peening (SP) is considered suitable for AM of engineering devices made of 17-4PH (X5CrNiCuNb16-4) stainless steel. The objective of this study was to determine the effect of three types of peening media (CrNi steel shot, glass, and ceramic beads) on the corrosion resistance of specimens of DMLS 17-4PH stainless steel. Results demonstrated that SP caused steel microstructure refinement and induced both martensite (α) formation and retained austenite (γ) reduction. 17-4PH specimens peened showed the increase in surface hardness of 255, 281, and 260 HV0.2 for ceramic, glass, and steel, respectively. DMLS 17-4PH specimens modified by SP exhibited different surface morphology, hardness, and microstructure and thus, these properties affect corrosion performance. The results implied that steel shot peened with steel shot showed the highest resistance to corrosion processes (Icorr = 0.019 μA/cm2), slightly worse with glass (Icorr = 0.227 μA/cm2) and ceramics (Icorr = 0.660 μA/cm2) peened. In the case of ceramic and glass beads, it was possible to confirm the presence of the above-mentioned particles in the surface layer after SP.

Metallic coatings based on cobalt and nickel are promising for elongating the life span of machine components operated in harsh environments. However, reports regarding the ambient temperature tribological performance and cavitation erosion resistance of popular MCrAlY (where M = Co, Ni or Co/Ni) and NiCrMoNbTa coatings are scant. This study comparatively investigates the effects of microstructure and hardness of HVOF deposited CoNiCrAlY, NiCoCrAlY and NiCrMoNbTa coatings on tribological and cavitation erosion performance. The cavitation erosion test was conducted using the vibratory method following the ASTM G32 standard. The tribological examination was done using a ball-on-disc tribometer. Analysis of the chemical composition, microstructure, phase composition and hardness reveal the dry sliding wear and cavitation erosion mechanisms. Coatings present increasing resistance to both sliding wear and cavitation erosion in the following order: NiCoCrAlY < CoNiCrAlY < NiCrMoNbTa. The tribological behaviour of coatings relies on abrasive grooving and oxidation of the wear products. In the case of NiCrMoNbTa coatings, abrasion is followed by the severe adhesive smearing of oxidised wear products which end in the lowest coefficient of friction and wear rate. Cavitation erosion is initiated at microstructure discontinuities and ends with severe surface pitting. CoNiCrAlY and NiCoCrAlY coatings present semi brittle behavior, whereas NiCrMoNbTa presents ductile mode and lesser surface pitting, which improves its anti-cavitation performance. The differences in microstructure of investigated coatings affect the wear and cavitation erosion performance more than the hardness itself.

The aim of the presented research was to investigate the mechanism of sorption of Cu(II) ions on the commercially available Purolite S 940 and Purolite S 950 chelating ion exchangers with the aminophosphonic functional groups. In order to understand better the sorption mechanism, the beads were cut with an ultramicrotome before and after the Cu(II) ion sorption process. The cut beads were examined by scanning electron microscopy (SEM) with an EDX detector. The performed linear profiles of the elemental composition allowed us to examine the depth with which the sorbed metal penetrates into. For further investigations concerning the mechanism of the sorption process, the Fourier transform infrared spectroscopy (FTIR) analysis using the attenuated total reflectance (ATR) technique and the X-ray photoelectron spectroscopy (XPS) methods have been used. The comparison of FTIR and XPS spectra before and after the sorption of Cu(II) ions showed that free electron pairs from nitrogen and oxygen in the aminophosphonic functional groups participate in the process of copper ion sorption. In addition, the microscopic studies suggested that the process of ion exchange between Na(I) ions and sorbed Cu(II) ions takes place on the Purolite S 940 and Purolite S 950. This study concerning the in-depth understanding the of Cu(II) sorption mechanism, using modern analytical tools and research methods could be very useful for its further modifications leading to the improvement of the process efficiency.

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