No abstract

No abstract

No abstract

Polymer concrete (PC) is a commonly used material in construction due to its improved durability and good bond strength to steel substrate. PC has been suggested as a repair and seal material to restore the bond between the cement annulus and the steel casing in wells that penetrate formations under consideration for CO 2 sequestration. Nanoparticles including Multi-Walled Carbon Nano Tubes (MWCNTs), Aluminum Nanoparticles (ANPs) and Silica Nano particles (SNPs) were added to an epoxy-based PC to examine how the nanoparticles affect the bond strength of PC to a steel substrate. Slant shear tests were used to determine the bond strength of PC incorporating nanomaterials to steel; resultsreveal that PC incorporating nanomaterials has an improved bond strength to steel substrate compared with neat PC. In particular, ANPs improve the bond strength by 51% over neat PC. Local shear stresses, extracted from Finite Element (FE)analysis of the slant shear test, were foundto be as much as twice the apparent/averageshear/bond strength. These results suggest that the impact of nanomaterials is higher than that shown by the apparent strength. Fourier Transform Infrared (FTIR) measurements of epoxy with and without nanomaterials showed ANPs to influence curing of epoxy, which might explain the improved bond strength of PC incorporating ANPs.

Polymer concrete (PC) are used in bridge deck overlays due to its superior durability specifically freeze-thaw and corrosion resistance. The excellent durability of PC is related to its impermeable microstructure and good bond to concrete or steel substrates. However, there is an increasing need to improve PC resistance to crack propagation (fracture toughness) to enhance its fatigue resistance and extend its service life. Researchers showed that objective becomes possible using dispersed chopped synthetic fibers (6-12 mm long). However, this approach was criticized for its dramatic impact on PC flowability. Here we suggest improving fracture toughness of PC using Multi-Walled Carbon Nanotubes (MWCNTs).PC mixes were produced using epoxy and standard aggregate with varying contents of MWCNTs being: 0 (Neat), 0.5, 1.0, 1.5 and 2.0 wt.% by weight of epoxy. Flowability of PC incorporating MWCNTs was tested. The tensile strength of PC incorporating MWCNTs was evaluated using direct tension test. A closed loop notched beam three-point bending test fracture test was used to evaluate fracture toughness of PC. The crack mouth opening displacement (CMOD) clip gage was used to provide feedback. The inverse analysis approach was used to extract the bilinear stress-crack opening displacement relation and calculate the fracture toughness (GF) of PC with and without MWCNTs. It is shown that MWCNTs significantly improves the fracture toughness and toughness of PC without significantly impacting its flowability. Microstructural analysis using Fourier Transform Infrared Analysis (FTIR) of polymer used to produce PC explains the effect of incorporating MWCNTs.