Statistics show that more than 700 thousand tons of dye are produced annually across the globe. Around 10–20% of this is used in industrial processes such as printing and dyeing, while about 50% of the dye produced is discharged into the environment without proper physicochemical treatment. Even trace amounts of dye in water can reduce oxygen solubility and have carcinogenic, mutagenic, and toxic effects on aquatic organisms. Therefore, before dye-containing wastewater is discharged into the environment, it must be properly treated. The present study investigates the green synthesis of nickel ferrite NiFe2O4 (NIFE) spinel magnetic nanoparticles (MNPs) via chemical coprecipitation of a solution of Ni2+/Fe3+ in the presence of a biopolymer blend of chitosan (CT) and ascorbic acid (AS). The magnetic nanomaterial was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy–energy dispersive X-ray analysis (SEM-EDX), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis), differential scanning calorimetry (DSC), and vibrating-sample magnetometry (VSM). The material was further explored as a catalyst for the photocatalytic degradation of malachite green (MG) under visible light irradiation coupled with ultrasonic waves. The combination of 90 min of visible solar light irradiation with 6.35 W·mL−1 ultrasonic power at pH 8 resulted in 99% of the photocatalytic efficiency of chitosan-ascorbic acid@NIFE (CTAS@NIFE) catalyst for 70 mg·L−1 MG. The quenching of the photocatalytic efficiency from 98% to 64% in the presence of isopropyl alcohol (IPA) suggested the involvement of hydroxy (•OH) radicals in the mineralization process of MG. The high regression coefficients (R2) of 0.99 for 35, 55, and 70 mg·L−1 MG indicated the sonophotocatalysis of MG by CTAS@NIFE was best defined by a pseudo first-order kinetic model. The mechanism involves the adsorption of MG on the catalyst surface in the first step and thereby mineralization of the MG by the generated hydroxyl radicals (•OH) under the influence of visible radiation coupled with 6.34 W·mL−1 ultrasonic power. In the present study the application of photodegradation process with sonochemistry results in 99% of MG mineralization without effecting the material structure unlike happens in the case adsorption process. So, the secondary pollution (generally happens in case of adsorption) can be avoided by reusing the spent material for another application instead of disposing it. Thus, the ecofriendly synthesis protocol, ease in design of experimentation like use of solar irradiation instead of electric power lamps, reusability and high efficiency of the material suggested the study to be potentially economical for industrial development at pilot scale towards wastewater remediation.
The contamination of water is increasing day by day due to the increase of urbanization and population. Textile industries contribute to this by discarding their waste directly into water streams without proper treatment. A recent study explores the treatment potential of copper oxide nanorods (CuO NRs) synthesized on a green basis in the presence of a biopolymer matrix of agar (AA) and alginate (Alg), in terms of cost effectiveness and environmental impact. The synthesized bio nanocomposite (BNC) was characterized by using different instrumental techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), ultra-violet spectroscopy (UV-Vis), scanning electron microscopy-energy dispersive X-ray-elemental analysis (SEM-EDX), transmission electron microscopy (TEM), selected area diffraction pattern (SAED) and X-ray photoelectron spectroscopy (XPS). The optical studies revealed that immobilization of CuO NRs with Alg-Agar biopolymer blend resulted in an increase in light absorption capacity by decreasing the energy bandgap from 2.53 eV to 2.37 eV. The bio nanocomposite was utilized as a photocatalyst for the degradation of amaranth (AN) dye from an aquatic environment under visible light irradiation. A statistical tool known as central composite design (CCD) associated with response surface methodology (RSM) was taken into consideration to evaluate the optimized values of process variables and their synergistic effect on photocatalytic efficiency. The optimized values of process variables were found to be irradiation time (45 min), AN concentration (80 ppm), catalyst dose (20 mg), and pH (4), resulting in 95.69% of dye degradation at 95% confidence level with desirability level 1. The rate of AN degradation was best defined by pseudo-first-order reaction based on the correlation coefficient value (R2 = 0.99) suggesting the establishment of adsorption-desorption equilibrium initially at the catalyst surface then photogenerated •O2– radicals interacting with AN molecule to mineralize them into small non-toxic entities like CO2, H2O. The material used has high efficiency and stability in photocatalytic degradation experiments up to four cycles of reusability.
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